Lab NotesWinter 2021 - Volume 57, Issue 4, Winter 2021, Vol. 57, No. 4

Flux-Induced Fingerprints in Flame-Fusion Synthetic Sapphire

Michaela Stephan

A 2.81 ct flame-fusion synthetic sapphire.
Figure 1. Face-up view of the 2.81 ct flame-fusion synthetic sapphire with flux fingerprints. Photo by Diego Sanchez.

The Carlsbad laboratory recently received a blue cushion mixed cut measuring 9.07 × 7.07 × 4.62 mm (figure 1). Standard gemological testing gave a refractive index of 1.760–1.768, consistent with sapphire. Microscopic examination uncovered a fingerprint resembling those found in natural sapphires (figure 2). Closer examination revealed the fingerprint to be a flux fingerprint. When the stone was immersed in mineral oil, curved color banding diagnostic of flame-fusion lab-grown sapphire became visible (figure 3).

Flux fingerprint in the flame-fusion synthetic sapphire.
Figure 2. This flux fingerprint in the lab-grown sapphire is similar to the fingerprints found in natural sapphire. Photomicrograph by Nathan Renfro and Michaela Stephan; field of view 1.76 mm.
Curved color banding is seen when immersed in mineral oil.
Figure 3. When immersed in mineral oil, curved color banding is visible along with a natural-looking flux fingerprint and large gas bubbles. Photomicrograph by Nathan Renfro and Michaela Stephan; field of view 7.19 mm.

Typically, a flame-fusion-grown ruby or sapphire with healed fractures has undergone a process known as “quench crackling,” where fractures are created in the stone by heating and subsequent rapid cooling. This stone did not show the characteristic cellular fracturing created by this process, making the healed fractures appear even more natural. The randomly fractured stone had been immersed in a flux melt. The flux melt filled and partially healed the fractures while the stone gradually cooled, which resulted in natural-looking fingerprints of residual flux. This treatment is usually seen in flame-fusion synthetic rubies (K. Schmetzer and F.-J Schupp, “Flux-induced fingerprint patterns in synthetic ruby: An update,” Spring 1994 G&G, pp. 33–38).

Michaela Stephan is a staff gemologist at GIA in Carlsbad, California.

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